Preparation and Properties of a Sulphoaluminate Magnesium-Potassium Phosphate Green Cementitious Composite Material from Industrial Solid Wastes

Abstract

The preparation of high-performance green cementitious material from industrial solid waste is a feasible large-scale utilization approach for industrial solid waste. This work investigates the feasibility of using industrial solid wastes in a sulphoaluminate–magnesium–potassium–phosphate cementitious composite material (SAC-MKPC) clinker preparation and the influence of the calcination temperature and clinker ingredients on the hydration behavior and mechanisms of the SAC-MKPC with a Mg/P ratio of 5. The results show that the novel SAC-MKPC that was prepared from aluminum slag, carbide slag, coal gangue, and magnesium desulfurization slag was composed mainly of mineral MgO, C4A3S¯, and C2S and the calcination temperature of the main mineral phases was 1250–1350 °C. The solid-waste-based SAC-MKPC had better mechanical properties and excellent water resistance compared with the MKPC. The optimal compressive strength reached 35.2, 70.9, 84.1, 87.7, and 101.6 MPa at 2 h, 1 d, 3 d, 7 d, and 28 d of hydration, respectively. The X-ray diffraction spectra and scanning electron micrographs of the hydration products of the SAC-MKPC clinker showed that AFt and K-struvite crystals coexisted and adhered to form a dense structure. This work provides an innovative idea to produce green cementitious material using industrial solid wastes and may promote the sustainable development of the power and mining industries.