Assessment and Review of Heavy Metals Pollution in Sediments of the Mediterranean Sea

Author:

Robledo Ardila Pedro Agustín1ORCID,Álvarez-Alonso Rebeca1ORCID,Árcega-Cabrera Flor2,Durán Valsero Juan José3ORCID,Morales García Raquel3,Lamas-Cosío Elizabeth2,Oceguera-Vargas Ismael2,DelValls Angel45ORCID

Affiliation:

1. IGME-CSIC, NC Geological Survey of Spain, Spanish National Research Council, Balearic Island Unit, Carrer de Felicià Fuster, 7, 07006 Palma de Mallorca, Spain

2. Unidad de Química en Sisal, Facultad de Química, Universidad Nacional Autónoma de México, Puerto de Abrigo S/N, Sisal 97355, Yucatán, Mexico

3. IGME-CSIC, NC Geological Survey of Spain, Spanish National Research Council, C/ Ríos Rosas, 23, 28003 Madrid, Spain

4. Environmental Science and Technology Department, University of Santa Cecilia, Santos 11045-907, Brazil

5. Water Challenge, S.L., Centro de I+D+I, C/Alamo Carolino s/n, Poligono Industrial Fuente de Rey, 41703 Dos Hermanas, Sevilla, Spain

Abstract

The impact of marine sediment pollution is crucial for the health of the seas, particularly in densely populated coastal areas worldwide. This study assesses the concentration and distribution of heavy metals in the marine sediments of the main regions of the Mediterranean Sea. The results underscore high concentrations of mercury (Hg), nickel (Ni), and copper (Cu), whereas chromium (Cr), zinc (Zn), cadmium (Cd), barium (Ba), and vanadium (V) exhibit moderate values. To assess the heavy metal results, sediment quality guidelines and pollution indices (Igeo and Geochemical Signal Type-GST) were employed, revealing a consistent trend of decreasing concentrations from the coastal zone to the open sea. Principal Component Analysis (PCA) emphasizes the significant roles of Cu, Zn, Ba, and Cr in sediment chemistry. The study suggests that the distribution patterns of heavy metals are linked to wastewater discharges in coastal areas, requiring effective management strategies to ensure the health of the Mediterranean Sea.

Funder

Geological and Mining Institute of Spain

Spanish National Research Council

Publisher

MDPI AG

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