Potential of the Oxidized Form of the Oleuropein Aglycon to Monitor the Oil Quality Evolution of Commercial Extra-Virgin Olive Oils

Author:

Esposto Sonia1ORCID,Urbani Stefania1,Selvaggini Roberto1ORCID,Taticchi Agnese1,Gallina Toschi Tullia2ORCID,Daidone Luigi1,Bendini Alessandra2ORCID,Veneziani Gianluca1ORCID,Sordini Beatrice1ORCID,Servili Maurizio1ORCID

Affiliation:

1. Department of Agricultural, Food and Environmental Sciences, University of Perugia, 06126 Perugia, Italy

2. Department of Agricultural and Food Sciences, University of Bologna, 40126 Bologna, Italy

Abstract

The quality of commercially available extra-virgin olive oils (VOOs) of different chemical compositions was evaluated as a function of storage (12 months), simulating market storage conditions, to find reliable and early markers of the virgin olive oil (VOOs) quality status in the market. By applying a D-optimal design using the Most Descriptive Compound (MDC) algorithm, 20 virgin olive oils were selected. The initial concentrations of oleic acid, hydrophilic phenols, and α-tocopherol in the 20 VOOs ranged from 58.2 to 80.5%, 186.7 to 1003.2 mg/kg, and 170.7–300.6 mg/kg, respectively. K270, ∆K, (E, E)-2.4-decadienal and (E)-2-decenal, and the oxidative form of the oleuropein aglycon (3,4-DHPEA-EA-OX) reflected the VOO quality status well, with 3,4-DHPEA-EA-OX being the most relevant and quick index for simple monitoring of the “extra-virgin” commercial shelf-life category. Its HPLC-DAD evaluation is easy because of the different wavelength absorbances of the oxidized and non-oxidized form (3,4-DHPEA-EA), respectively, at 347 and 278 nm.

Funder

the European Commission within the Horizon 2020 Framework Program

Publisher

MDPI AG

Subject

Plant Science,Health Professions (miscellaneous),Health (social science),Microbiology,Food Science

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