Green-Emitting Carbon Quantum Dots: Highly Sensitive Temperature Sensing Probe in Nanocomposite and Lubrication System

Author:

Sun Jiannan1,Yan Ke1ORCID,Zhang Pan1,Pan Aizhao2,Chen Xuehang1,Shi Xinyi1

Affiliation:

1. Key Laboratory of Education Ministry for Modern Design & Rotor-Bearing System, Xi’an Jiaotong University, Xi’an 710049, China

2. Department of Chemistry, School of Chemistry, Xi’an Jiaotong University, Xi’an 710049, China

Abstract

Carbon quantum dots (CQDs) have already demonstrated their utility as lubricant additives, and non-contact temperature sensing based on CQDs offers considerable potential for condition monitoring in mechanical, electrical, and other fields, as well as lubrication-temperature multifunctional applications in lubricants. In this paper, we have successfully synthesized and designed high-brightness carbon quantum dots/polyvinyl alcohol (PVA) temperature sensor thin film and dispersions of CQDs in a liquid paraffin lubrication system. Based on fluorescence intensity and the fluorescence intensity ratio, the carbon quantum dot/PVA film exhibited exponential temperature-dependent properties with a wide applicability range, a high goodness of fit (R2 > 0.99), and high relative thermal sensitivity (relative sensitivities of 1.74% K−1 and 1.39% K−1 for fluorescence intensity and fluorescence intensity ratio, respectively). In addition, based on the fluorescence intensity, the CQDs exhibited a wide temperature range (20–90 °C), a high goodness of fit (R2 > 0.99), and higher sensitivity (2.84% K−1) in a liquid paraffin lubrication system, which reflects the temperature responsive properties of carbon quantum dots as additives in lubrication systems. These findings provide convenient and effective possibilities for the sensing and monitoring of carbon quantum dots and their multifunctional applications under lubrication systems.

Funder

National Natural Science Foundation of China

Key Special Project of Ministry of Industry and Information Technology

Publisher

MDPI AG

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