Reinforcing Efficiency of Recycled Carbon Fiber PLA Filament Suitable for Additive Manufacturing

Author:

Tammaro Loredana1ORCID,Martone Alfonso2ORCID,Palmieri Barbara2ORCID,Borriello Carmela1ORCID,Portofino Sabrina1,Iovane Pierpaolo1ORCID,Cilento Fabrizia2ORCID,Giordano Michele2ORCID,Galvagno Sergio1

Affiliation:

1. Nanomaterials and Devices Laboratory, Department for Sustainability, Sustainability Materials Technology and Processes, ENEA, P.le E. Fermi, 1, 80055 Portici, Italy

2. Institute of Polymers, Composite and Biomaterials (IPCB), National Research Council, P.le E. Fermi, 1, 80055 Portici, Italy

Abstract

The use of 3D printing technology for manufacturing new products based on sustainable materials enables one to take advantage of secondary raw materials derived from recycling. This work investigates the structural performances of 3D printing composite filaments based on polylactic acid (PLA), as a matrix, reinforced by recycled carbon fiber (rCF). Carbon fibers were recovered from industrial scraps by a patented thermal process and used to produce thermoplastic composite filaments for additive manufacturing without any additional treatment and additives. The influence of the recovered carbon fiber (rCF) content on the thermal properties, mechanical properties and microstructure of the composites was studied in the range of 3–20 wt%. The recorded TGA curves exhibited a one-stage weight loss within the temperature range 290–380 °C for all samples and the residual rCF content was in good agreement with the theoretical fiber loading. The Young modulus of the extruded filaments strongly increased below a critical content (5 wt%), while at higher content the improvement was reduced. An increase in the storage modulus of 54% compared to neat PLA 3D printed sample resulted in a printed specimen with a higher rCF content. SEM images highlighted a strong rCF prevailing alignment in the direction of the extrusion flow, creating almost unidirectional reinforcement inside the filament. These findings suggest that homogeneous composite filaments reinforced with well-dispersed recycled CF without additional chemical modification and additives are suitable materials for additive manufacturing. The effect of rCF topological distribution within the material on the mechanical performances has been discussed, highlighting that the isolated fibers could efficiently transfer loads with respect to the percolated 3D network and have been correlated with the microstructure.

Funder

Ministry of Industry and Made in Italy

Publisher

MDPI AG

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