Recent Progress in Spinel Ferrite (MFe2O4) Chemiresistive Based Gas Sensors

Author:

Zhang Run1,Qin Cong2,Bala Hari1,Wang Yan34,Cao Jianliang24ORCID

Affiliation:

1. School of Materials Science and Engineering, Henan Polytechnic University, Jiaozuo 454000, China

2. College of Chemistry and Chemical Engineering, Henan Polytechnic University, Jiaozuo 454000, China

3. College of Safety Science and Engineering, Henan Polytechnic University, Jiaozuo 454003, China

4. State Collaborative Innovation Center of Coal Work Safety and Clean-Efficiency Utilization, Henan Polytechnic University, Jiaozuo 454003, China

Abstract

Gas-sensing technology has gained significant attention in recent years due to the increasing concern for environmental safety and human health caused by reactive gases. In particular, spinel ferrite (MFe2O4), a metal oxide semiconductor with a spinel structure, has emerged as a promising material for gas-sensing applications. This review article aims to provide an overview of the latest developments in spinel-ferrite-based gas sensors. It begins by discussing the gas-sensing mechanism of spinel ferrite sensors, which involves the interaction between the target gas molecules and the surface of the sensor material. The unique properties of spinel ferrite, such as its high surface area, tunable bandgap, and excellent stability, contribute to its gas-sensing capabilities. The article then delves into recent advancements in gas sensors based on spinel ferrite, focusing on various aspects such as microstructures, element doping, and heterostructure materials. The microstructure of spinel ferrite can be tailored to enhance the gas-sensing performance by controlling factors such as the grain size, porosity, and surface area. Element doping, such as incorporating transition metal ions, can further enhance the gas-sensing properties by modifying the electronic structure and surface chemistry of the sensor material. Additionally, the integration of spinel ferrite with other semiconductors in heterostructure configurations has shown potential for improving the selectivity and overall sensing performance. Furthermore, the article suggests that the combination of spinel ferrite and semiconductors can enhance the selectivity, stability, and sensing performance of gas sensors at room or low temperatures. This is particularly important for practical applications where real-time and accurate gas detection is crucial. In conclusion, this review highlights the potential of spinel-ferrite-based gas sensors and provides insights into the latest advancements in this field. The combination of spinel ferrite with other materials and the optimization of sensor parameters offer opportunities for the development of highly efficient and reliable gas-sensing devices for early detection and warning systems.

Funder

National Natural Science Foundation of China

Program for Science and Technology Innovative Research Team at the University of Henan Province

Natural Science Foundation of Henan Province

Key Science and Technology Program of Henan Province

Fundamental Research Funds for the Universities of Henan Province

Key Scientific Research Projects of Colleges and Universities in Henan Province

Publisher

MDPI AG

Subject

General Materials Science,General Chemical Engineering

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