Fabrication of Bamboo-Based Activated Carbon for Low-Level CO2 Adsorption toward Sustainable Indoor Air

Abstract

This study fabricated a low-cost activated carbon (AC) adsorbent from readily available bamboo trees to control indoor CO2 levels and reduce energy costs associated with sustaining clean indoor air. Bamboo is naturally high in potassium content and has narrow fibrous channels that could enhance selective CO2 adsorption. The prepared bamboo-based activated carbon (BAC) exhibits predominantly micropores with an average pore size of 0.17 nm and a specific surface area of 984 m2/g. Upon amination, amine functionalities, such as pyridine, pyrrole, and quaternary N, were formed on its surface, enhancing its CO2 adsorption capacity of 0.98 and 1.80 mmol/g for low-level (3000 ppm) and pure CO2 flows at the ambient condition, respectively. In addition, the 0.3% CO2/N2 selectivity (αs,g) of the prepared sorbents revealed a superior affinity of CO2 by BAC (8.60) over coconut shell-based adsorbents (1.16–1.38). Furthermore, amination enhanced BAC’s CO2αs,g to 13.4. These results exhibit this sustainable approach’s potential capabilities to ensure the control of indoor CO2 levels, thereby reducing the cost associated with mechanical ventilation systems. Further research should test the new sorbent’s adsorption properties (isotherm, kinetics, and thermodynamics) for real-life applicability.