Affiliation:
1. Key Laboratory of the Ministry of Education for Advanced Catalysis Materials College of Chemistry and Materials Science Zhejiang Normal University 688 Yingbin Road Jinhua 321004 P.R. China
Abstract
AbstractHerein, the tandem synthesis of various CF3Se‐containing heterocyclic compounds has been developed, using Tf2O as the catalyst and trifluoromethyl selenoxides as the electrophilic trifluoromethylselenolation reagents. This process is characterized by its mild conditions, ease of operation, and good functional group compatibility. A variety of alkynes could be transferred into CF3Se‐containing indoles, benzofurans, benzothiophenes, isoquinolines and chromenes in good yields. A key step involving the formation of the electrophilic CF3Se species was proposed.
Funder
National Natural Science Foundation of China
Natural Science Foundation of Zhejiang Province
Zhejiang Normal University
Subject
General Chemistry,Catalysis,Organic Chemistry
Cited by
1 articles.
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