Affiliation:
1. Henan International Joint Laboratory of Rare Earth Composite Material College of Materials Engineering Henan University of Engineering Zhengzhou 451191 P. R. China
2. Green Catalysis Center College of Chemistry Zhengzhou University Zhengzhou 450001 P. R. China
3. National Key Laboratory of Cotton Bio Breeding and Integrated Utilization Institute of Cotton Research Chinese Academy of Agricultural Sciences Anyang 455000 P. R. China
Abstract
AbstractElemental white phosphorous (P4) is a crucial feedstock for the entire phosphorus‐derived chemical industry, serving as a common precursor for the ultimate preparation of high‐grade monophosphorus (P1) fine chemicals. However, the corresponding manufacturing processes generally suffer from a deep reliance on hazardous reagents, inputs of immense energy, emissions of toxic pollutants, and the generation of substantial waste, which have negative impacts on the environment. In this context, sustainability and safety concerns provide a consistent impetus for the urgent overall improvement of phosphorus cycles. In this Concept, we present an overview of the most recent growth in photo‐ and electrochemical synthesis of P1 organo‐compounds from P4, with special emphasis on sustainable features. The key aspects of innovations regarding activation mode and mechanism have been comprehensively analyzed. A preliminary look at the possible future direction of development is also provided.
Funder
National Natural Science Foundation of China
Subject
General Chemistry,Catalysis,Organic Chemistry