Affiliation:
1. School of Chemistry University of Glagsow G12 8QQ Glasgow UK
Abstract
AbstractGels formed using a perylene bisimide (PBI) as a low molecular weight gelator can show the photothermal effect. Formation of the PBI radical anion results in new absorption bands forming, meaning that subsequent irradiation with a wavelength of light overlapping with the new absorption band leads to heating of the gel. This approach can be used to heat the gel, as well as the surrounding milieu. We show how we can use electrochemical methods as well as multicomponent systems to form the radical anion without the need for UV light, and how we can use the photothermal effect to induce phase transitions in the solutions above the gels by exploiting photothermal behavior.
Funder
Engineering and Physical Sciences Research Council
UK Research and Innovation
Leverhulme Trust
Subject
General Chemistry,Catalysis,Organic Chemistry