Visible‐Light‐Promoted Electron Donor‐Acceptor Complex Enabled Decarboxylative Alkylation of Quinoxalin‐2(1H)‐ones and N‐Hydroxyphthalimide Esters with Na2S as a Catalytic Donor

Author:

Song Hai‐Yang1,Zhang Zhuo‐Tao1,Tan Hong‐Yu1,Lu Yu‐Han1,Yang Tian‐Bao2,Chen Jin‐Yang1,Ji Hong‐Tao1,He Wei‐Min1ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering University of South China Hengyang 421001 P. R. China

2. National Engineering Research Center of Low-Carbon Processing and Utilization of Forest Biomass Nanjing Forestry University Nanjing 210037 P. R. China

Abstract

AbstractWe developed a novel and efficient method for the synthesis of various 3‐alkylated quinoxalin‐2(1H)‐ones (32 examples, 70%–96% yields) through electron donor‐acceptor complex enabled alkylation of quinoxalin‐2(1H)‐ones with N‐ hydroxyphthalimide esters as the alkyl source and Na2S as the catalytic electron donor under external photocatalyst‐, oxidant‐ and additive‐free conditions.

Funder

University of South China

Publisher

Wiley

Subject

Organic Chemistry

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