1,3‐Diketone‐Mediated Synthesis of Symmetrical Aryl Imides from Activated Amides

Author:

Park Myeong Seong1,Rajamanickam Karthik Rajan1,Song Kwang Ho2,Lee Sunwoo1ORCID

Affiliation:

1. Department of Chemistry Chonnam National University Gwangju 61186 Republic of Korea

2. Department of Chemical & Biological Engineering Korea University Seoul 02841 Republic of Korea

Abstract

AbstractSymmetrical aryl imides are synthesized from the reaction of activated amides such as N‐phenyl‐N‐tosyl benzamides. The amine source is provided by lithium hexamethyldisilazide (LiHMDS), and a 1,3‐diketone mediates the generation of the N‐acyl donor from N,N‐bis(trimethylsilyl)amide. Various symmetrical aryl amides are thus formed in moderate to good yields.

Publisher

Wiley

Subject

Organic Chemistry

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