Spectroscopic pressure investigation of a novel high energy system

Author:

Neal Sabine N.1,Patel Rajen B.2,Stepanov Victor2,Tenney Samuel A.1ORCID

Affiliation:

1. Brookhaven National Laboratory Center for Functional Nanomaterials Upton NY 11973 USA

2. U.S. Army Explosives Research Branch DEVCOM-AC Picatinny Arsenal Wharton NJ 07806 USA

Abstract

AbstractThis work combines a novel multimodal spectroscopic technique, O‐PTIR and Raman spectroscopy, which allows for the simultaneous collection of infrared and Raman spectra, with traditional diamond anvil cell techniques to explore pressure induced phase transitions in a high energy material. Two phase transitions are revealed, with the first transition emerging below 0.23 GPa, to a higher order phase, followed by a broad transition to a lower order phase. Aside from the pressure studies, hyperspectral imaging was performed, confirming the homogeneous nature of the system.

Publisher

Wiley

Subject

General Chemical Engineering,General Chemistry

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