Affiliation:
1. The Chair of Crystal Chemistry and Technology D.Mendeleyev University of Chemical Technology of Russia Miusskaya pl. 9 Moscow 125047 Russia
Abstract
Homogeneity regions of ZnTe, CdTe, CdSe, and CdS were determined by the direct physic‐chemical “extraction” technique combined with the high temperature equilibrium freezing technique. The general scheme of homogeneity range for all studied compounds has been constructed according to which “wurtzite‐zincblende” transition occurred by peritectic reactions from both Metal and Chalcogen rich sides. The analysis of nonstoichiometry as a solid solution of an over‐stoichiometric component in the above compounds has been fulfilled. The thermodynamic parameters of stability of “wurtzite‐zincblende” transition were estimated.
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10 articles.
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