Selective Metal‐free HB(C6F5)2 Catalyzed Allene Cyclotrimerization: Formation of 1,3,5‐Trimethylenecyclohexane and Its Tris‐hydroboration Product-Reference-Cited by-同舟云学术

Selective Metal‐free HB(C₆F₅)₂ Catalyzed Allene Cyclotrimerization: Formation of 1,3,5‐Trimethylenecyclohexane and Its Tris‐hydroboration Product

Published:2016-12-22 Issue:5 Volume:129 Page:1396-1400
ISSN:0044-8249
Container-title:Angewandte Chemie
language:en
Short-container-title:Angewandte Chemie

Author:

Tao Xin¹,Kehr Gerald¹,Daniliuc Constantin G.¹,Erker Gerhard¹

Affiliation:

1. Organisch-Chemisches Institut Westfälische Wilhelm-Universität Münster Corrensstr. 40 48149 Münster Germany

Abstract

AbstractAllene is cyclotrimerized under metal‐free conditions with the borane HB(C6F5)2 catalyst to selectively give 1,3,5‐trimethylenecyclohexane (3 a). Three‐fold hydroboration of the 1,3,5‐cyclotrimer with Piers’ borane gives the all‐cis 1,3,5‐CH2B(C6F5)2 substituted cyclohexane product 14.

Publisher

Wiley

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/ange.201610530

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