Affiliation:
1. Department of Chemistry Banaras Hindu University Varanasi 221005 India
2. Department of Chemistry Howard University 525 College Street NW Washington DC 20059 USA
Abstract
Three novel Cd(II) metal complexes 1–3 have been synthesized with different derivatives of thiazoline, hydrazide and carbodithioate. These metal complexes are abbreviated as [Cd (tht)2]n, [Cd (Hpph)2]n and [Cd (mpps)2]n along with their respective ligands Htht, H2pph and mpps. The developed metal complexes are characterized using X‐ray diffraction (XRD) data and other spectroscopic techniques (Infrared [IR], nuclear magnetic resonance [NMR], ultraviolet–visible [UV–vis] and fluorescence). The polymeric nature of these cadmium complexes have been ascertained by single XRD data. Several significant interactions were also revealed, which aid in the stabilization of these complexes' supramolecular architecture. Comparing complex 2 with complexes 1 and 3, the absorption spectra of complex 2 exhibits a greater λmax. On comparing the fluorescence study of these complexes, complex 2 has a higher fluorescence than complexes 1 and 3. The cyclic voltammetry (CV) approach was employed to detect the electrochemical behaviour of these complexes, as well as the sensing of uric acid (UA) by these complexes via modified glassy carbon electrodes (GCEs). According to the conclusions received by CV study, the modified electrode containing complex 3 has admirable UA electro catalytic activity. This UA electrochemical sensing device offers a low detection limit (0.3 μM), fine linear ranges (30–1500 μM), reasonable sensitivity, and a fast reaction time.
Subject
Inorganic Chemistry,General Chemistry
Cited by
8 articles.
订阅此论文施引文献
订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献
1. Anti-cancer activities based on ZnII complex of potassium 5-thiophen-2-yl-[1,3,4]-oxadiazole-2-thiolate: Synthesis, crystal structure, photoluminescence study and Hirshfeld analysis;Journal of Molecular Structure;2024-10
2. Fluorinated‐Thiolate Osmium(III) and Osmium(IV) Complexes Bearing N,N‐diethyldithiocarbamate and Substituted Phosphines. Synthesis, Crystal Structures and DFT‐Studies;Helvetica Chimica Acta;2024-08-26
3. Zn(II) and Cd(II) complexes of dithiocarbamate ligands: synthesis, characterization, anticancer, and theoretical studies;Journal of Sulfur Chemistry;2024-08-02
4. Tunability of Photovoltaic Functions via Halogen Substitution [(Ade)2 CdX4](X = Cl, Br): A Class of Three-Dimensional Organic–Inorganic Hybrid Materials;Molecules;2024-06-11
5. CoII-catalysed synthesis of N-(4-methoxyphenyl)-5-(pyridin-4-yl)-1,3,4-oxadiazol-2-amine hemihydrochloride monohydrate;Acta Crystallographica Section E Crystallographic Communications;2024-03-12