3<i>H</i>‐Phenothiazin‐3‐one: A Photocatalyst for the Aerobic Photochemical Oxidation of Sulfides to Sulfoxides-Reference-Cited by-同舟云学术

3H‐Phenothiazin‐3‐one: A Photocatalyst for the Aerobic Photochemical Oxidation of Sulfides to Sulfoxides

Published:2023-07-27 Issue:15 Volume:365 Page:2643-2650
ISSN:1615-4150
Container-title:Advanced Synthesis & Catalysis
language:en
Short-container-title:Adv Synth Catal

Author:

Spyropoulou Chrysanthi K.¹,Skolia Elpida¹,Flesariu Dragos F.²,Zissimou Georgia A.²,Gkizis Petros L.¹,Triandafillidi Ierasia¹,Athanasiou Modestos³,Itskos Grigorios³,Koutentis Panayiotis A.²,Kokotos Christoforos G.¹^ORCID

Affiliation:

1. Laboratory of Organic Chemistry Department of Chemistry National and Kapodistrian University of Athens Panepistimiopolis, Athens 15771 Greece

2. Department of Chemistry University of Cyprus P.O. Box 20537 1678 Nicosia Cyprus

3. Experimental Condensed Matter Physics Laboratory Department of Physics University of Cyprus P.O. Box 20537 1678 Nicosia Cyprus

Abstract

AbstractIn this study, 3H‐phenothiazin‐3‐one is identified as a photocatalyst for the photochemical oxidation of sulfides to sulfoxides. This photocatalytic method uses a low catalyst loading (0.05 mol%), molecular oxygen as the sole oxidant, and a blue LED lamp as the irradiation source. It can be applied to the oxidation of both alkyl‐aryl and alkyl‐alkyl sulfides. Moreover, the method is also applicable in the synthesis of the known pharmaceutically active compounds Modafinil and Sulforaphane.

Funder

University of Cyprus

Agricultural Research Institute

Ministry of Agriculture - Saskatchewan

Publisher

Wiley

Subject

General Chemistry

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/adsc.202300516

Reference95 articles.

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