Affiliation:
1. School of Chemistry and Chemical Engineering Shanxi University Wucheng Road 92 Taiyuan 030006 People's Republic of China
2. Department of Chemistry and Chemical Engineering Hefei Normal University 230061 Hefei Anhui People's Republic of China
Abstract
AbstractA cobalt‐catalyzed intermolecular 1,2‐difunctionalization of alkenes with anilines/indoles and acetonitrile has been developed. This protocol provides an access to functionalized cyano‐containing molecules. In this transformation, employing di‐tert‐butyl peroxide as a radical initiator, a variety of commercialized nucleophiles and electronically diverse arenes were well tolerated. In addition, we also studied the kinetic isotope effect.
Funder
Shanxi Scholarship Council of China
Hefei Normal University