Recent Advances in Transition‐Metal‐Catalyzed Ring‐Retentive Addition Reactions of Oxa(aza)benzonorbornadienes

Author:

Lin Qifu1,Yang Dingqiao2ORCID

Affiliation:

1. College of Marine Sciences Beibu Gulf University Qinzhou 535011 People's Republic of China

2. Key Laboratory of Theoretical Chemistry of Environment Ministry of Education College of Chemistry South China Normal University Guangzhou 510006 People's Republic of China

Abstract

AbstractOxa(aza)benzonorbornadienes are utilized as important synthetic intermediates and useful building blocks in organic synthesis due to their structural features and reactivity. In addition to ring‐opening reactions, the transition‐metal‐catalyzed ring‐retentive addition reactions of oxa(aza)bicyclic alkenes have increasingly drawn the attention of various researchers. Numerous efficient protocols in this field have been investigated that enable facile and efficient transformations of oxa(aza)benzonorbornadienes to related valuable adducts, which are summarized and discussed in detail in this review.

Funder

Natural Science Foundation of Guangxi Zhuang Autonomous Region

Beibu Gulf University

Publisher

Wiley

Subject

General Chemistry

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