An Unexpected Boron Rearrangement Leads to a Fluorogenic and Colorimetric BODIPY Probe-Reference-Cited by-同舟云学术

An Unexpected Boron Rearrangement Leads to a Fluorogenic and Colorimetric BODIPY Probe

Published:2023-01-08 Issue:6 Volume:11 Page:
ISSN:2195-1071
Container-title:Advanced Optical Materials
language:en
Short-container-title:Advanced Optical Materials

Author:

Merkes Jean Michel¹²³,Raabe Gerhard²^ORCID,Kiessling Fabian¹³^ORCID,Rueping Magnus¹⁴^ORCID,Banala Srinivas¹²³^ORCID

Affiliation:

1. Institute for Experimental Molecular Imaging RWTH Aachen University Clinic Forckenbeckstrasse 55 52074 Aachen Germany

2. Institute of Organic Chemistry RWTH Aachen University Landoltweg 1 52074 Aachen Germany

3. Fraunhofer Institute for Digital Medicine MEVIS Max‐von‐Laue‐Straße 2 28359 Bremen Germany

4. KAUST Catalysis Centre (KCC) King Abdullah University of Science and Technology Thuwal 23955‐6900 Saudi Arabia

Abstract

AbstractThe isolation and characterization of a kinetically stable oxadiazaborinine (ODB) dye are described, which undergoes an unexpected thermal boron rearrangement with a color change and increase in fluorescence. This controllable reaction allows for the use as a practical time‐temperature indicator probe with the advantages of photostability, non‐reversibility, and environmental friendliness.

Publisher

Wiley

Subject

Atomic and Molecular Physics, and Optics,Electronic, Optical and Magnetic Materials

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/adom.202202601

Reference45 articles.

1. Boron Reagents in Synthesis

2. Boronic Acids as Bioorthogonal Probes for Site‐Selective Labeling of Proteins

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