Impact of Mixing Method on Rheological Instability for Binary Mixture of Linear Low‐Density Polyethylene

Author:

Seemork Jiraporn12,Itoh Tomoki1,Sako Takumi1,Wiwattananukul Rujirek1,Nobukawa Shogo13,Sasaki Hiroko4,Satoh Yasuo4,Yamaguchi Masayuki1

Affiliation:

1. School of Materials Science Japan Advanced Institute of Science and Technology 1‐1 Asahidai Nomi Ishikawa 923‐1292 Japan

2. Program in Petrochemistry Faculty of Science Chulalongkorn University Phayathai Rd. Bangkok 10330 Thailand

3. Materials Science and Engineering Nagoya Institute of Technology Gokiso‐cho Showa‐ku Nagoya Aichi 466‐8555 Japan

4. Prime Polymer Co., Ltd. 1‐5‐2 Higashi‐Shimbashi Minato‐ku Tokyo 105‐7122 Japan

Abstract

AbstractThe impact of different mixing methods on flow instability in capillary extrusion was examined using binary mixtures of linear low‐density polyethylene with different molecular weights. The polymers were blended using a single‐screw extruder, a twin‐screw extruder, and a twin‐screw mixer. The onset of flow instability changed depending on the mixing method used, even though their linear viscoelastic properties were almost identical. The mixtures that were subjected to mixing methods with weak mixing capability exhibit sharkskin failure even at low shear stress and low values of the maximum draw ratio without rupture in the molten state. The results suggested that mechanically weak points were present, which led to cohesive failure at the strand surface following abrupt stretching at the die exit (i.e., sharkskin failure). In contrast, the mixture that was subjected to thorough mixing exhibited smooth surface at high shear stress and a large maximum draw ratio.

Funder

JSPS Grant-in-Aid for Scientific Research (B)

Publisher

Wiley

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