Efficient extraction of hydrogen fluoride using hollow fiber membrane contactors with the aid of active‐learning

Author:

Park Jimin1ORCID,Cheon Mujin1,Kim David Inhyuk2,Park Daeseon2,Lee Jay H.3,Koh Dong‐Yeun14ORCID

Affiliation:

1. Department of Chemical and Biomolecular Engineering (BK21 Four) Korea Advanced Institute of Science and Technology Daejeon South Korea

2. EHS/Infra Technology Research Center Samsung Electronics Co., Ltd. Gyeonggi‐do South Korea

3. Department of Chemical Engineering and Materials Science University of Southern California Los Angeles California USA

4. Saudi Aramco – KAIST CO2 Management Center Daejeon South Korea

Abstract

AbstractThis study presents a sustainable approach to extracting hydrogen fluoride (HF) from wastewater using hollow fiber membrane contactors. HF, a widely used yet hazardous chemical, requires efficient separation techniques due to its environmental and health concerns. Our research compared two operational modes, vacuum mode and liquid–liquid extraction mode, revealing the latter as more efficient for HF separation. Notably, this study introduces a novel aspect by employing a data‐driven decision‐making method, Bayesian optimization (BO) for process optimization of the liquid–liquid extraction mode, aiming to maximize HF removal efficiency at low experimental costs. Subsequent validation through a 96‐h experimental run confirms the suitability of the optimized conditions for industrial applications. This study not only demonstrates an efficient HF separation process using hollow fiber membrane contactors but also establishes a new standard for complex industrial process optimization.

Funder

National Research Foundation of Korea

Samsung

Publisher

Wiley

Reference46 articles.

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3. Hydrofluoric acid burns: a review;Kirkpatrick JJR;Burns,1995

4. U.S. Environmental Protection Agency.Hydrogen fluoride (hydrofluoric acid);2016. Accessed April 10 2024.https://www.epa.gov/sites/default/files/2016-10/documents/hydrogen-fluoride.pdf

5. Hydrofluoric acid burns;Hatzifotis M;Burns,2004

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