Comprehensive performance of polycarbonate films doped with Tb(III) and Eu(III) complexes

Author:

Wu Fang1,Zhang Xinfei12,Wang Qi12,Yu Dayang1,Zheng Pan1,Zhu Rongli1,Wang Xu1,Pu Zejun1ORCID,Zhong Jiachun1

Affiliation:

1. School of Materials Science and Engineering, Material Corrosion and Protection Key Laboratory of Sichuan Province Sichuan University of Science and Engineering Zigong China

2. Shandong Yuanli Science and Technology Co. Ltd Weifang China

Abstract

AbstractIn order to expand the application of biobased polycarbonate in optical components, a series of isosorbide polycarbonate (PICC)/rare earth ion complex fluorescent composites were prepared by using PICC as a macromolecular ligand and Eu3+ and Tb3+ as rare earth luminescence centers. The coordination system between rare earth ions and PICC was investigated by Fourier transform infrared spectroscopy, DSC and TGA. On adjusting the ratio of Eu3+ and Tb3+, a PICC/rare earth ion composite with adjustable fluorescence color was obtained. Also, the thermal, mechanical and optical properties of a series of PICC/rare earth ion fluorescent films with different ratios were tested. A transparent fluorescent composite material with excellent mechanical properties and tunable fluorescent colors has been prepared. © 2024 Society of Industrial Chemistry.

Publisher

Wiley

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