Synthesis of 1‐Adamantylaminogermylene and Its Chalcogenation Reactions

Abstract

AbstractThe synthesis, isolation, and characterization of 1‐adamantylaminogermylene 1 have been achieved utilizing kinetic stabilization with a bulky aryl group on the germanium atom. Aminogermylene 1 was found to be stable in toluene solution at 110 °C for 3 days without decomposition. The chalcogenation reaction of 1 aiming to synthesize heavy amides gave the head‐to‐tail type dimers of the corresponding heavy amides.