Affiliation:
1. College of Chemistry, Chemical Engineering and Materials Science Soochow University Suzhou 215123 China
2. Yichang Ecological Environment Monitoring Center Department of Ecology and Environment of Hubei Province Yichang 443000 China
3. Provincial Key Laboratory of Gansu Higher Education for City Environmental Pollution Control, School of Chemical Engineering Lanzhou City University Lanzhou 730070 China
Abstract
AbstractBoron‐dipyrromethenes (BODIPYs) have attracted much attention owing to their unique properties and widespread applications; however, the incorporation of the heavier group 14 and 15 elements in the rigid dipyrromethene ligands remains limited. Herein, the dipyrromethene‐based heavier group 14 and 15 element complexes, tin‐dipyrromethene (SNDIPY, 1) and arsenic‐dipyrromethene (ASDIPY, 2), which are direct analogues of BODIPY, have been facilely synthesized and isolated in moderate yields. Both compounds have been investigated by NMR, UV‐vis absorption, photoluminescence spectroscopy, cyclic voltammogram, X‐ray crystallography, as well as theoretical studies. Both compounds exhibit green photoluminescence. Notably, SNDIPY 1 is air‐stable and compound 2 represents the first isolable and structurally characterized ASDIPY.
Funder
National Natural Science Foundation of China
Natural Science Foundation of Jiangsu Province
Cited by
2 articles.
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