Mn 2+ substitution within the {V 14 As 8 } polyoxovanadate archetype results in {Mn 2 V 12 As 8 } shells with trans ‐positioned heterometal positions
Author:
Affiliation:
1. Institute of Inorganic Chemistry Christian-Albrechts-University of Kiel Max-Eyth-Strasse 2 24118 Kiel Germany
2. Institute of Inorganic Chemistry RWTH Aachen University Landoltweg 1 D-52074 Aachen Germany
Publisher
Wiley
Subject
Inorganic Chemistry
Link
https://onlinelibrary.wiley.com/doi/pdf/10.1002/zaac.202100201
Reference51 articles.
1. A Novel Heterocluster withD3-Symmetry Containing Twenty-One Core Atoms: [As 6IIIV 15IVO42(H2O)]6⊖
2. [ASVV12VV2IVO40]7⊖, a Topologically Interesting, Mixed Valence Cluster as Model for Vanadium Minerals Formed by Weathering
3. A three-dimensional neutral framework of a novel decavanadium cluster bridged by an AsO4 tetrahedron: [AsVIV8VV2O26(μ-H2O)]·8H2O
4. A novel 2D arsenic vanadate network grafted with a transition metal complex: [Cu(phen)]2[VIVV4VAs2O19]·0.5H2OElectronic supplementary information (ESI) available: packing diagram, IR spectrum, TG curve and a plot of χM versus T for 1. See http://www.rsc.org/suppdata/dt/b2/b210589f/
5. Hydrothermal syntheses and structures of reduced and mixed valence polyoxovanadium clusters with capped cage cores: K3[H12(AsO)2(AsO4)V6IVV6VO36]·12H2O and Rb5 [(As2O)4(VO)2V12IVO36Cl]·2H2O
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