Affiliation:
1. Enamine Ltd. (www.enamine.net) Winston Churchill Street 78 Kyїv 02094 Ukraine
2. Taras Shevchenko National University of Kyiv Volodymyrska Street 60 Kyїv 01601 Ukraine
Abstract
AbstractChemoselective transformations of functionalized sulfonyl fluorides and chlorides are surveyed comprehensively. It is shown that sulfonyl fluorides provide an excellent selectivity control in their reactions. Thus, numerous conditions are tolerated by the SO2F group – from amide and ester formation to directed ortho‐lithiation and transition‐metal‐catalyzed cross‐couplings. Meanwhile, sulfur (VI) fluoride exchange (SuFEx) is also compatible with numerous functional groups, thus confirming its title of “another click reaction”. On the contrary, with a few exceptions, most transformations of functionalized sulfonyl chlorides typically occur at the SO2Cl moiety.
Funder
Enamine
Ministry of Education and Science of Ukraine
Subject
Materials Chemistry,General Chemical Engineering,Biochemistry,General Chemistry
Cited by
1 articles.
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1. Chemistry in Ukraine;The Chemical Record;2024-01-29