Metal–Organic Frameworks Photocatalyst Through Plasmon‐Induced Hot‐Electrons

Author:

Zorlu Tolga1ORCID,Becerril‐Castro I. Brian1ORCID,Sousa‐Castillo Ana2ORCID,Puértolas Begoña2ORCID,Besteiro Lucas V.2ORCID,Wang Zhiming3,Govorov Alexander4ORCID,Correa‐Duarte Miguel A.2ORCID,Alvarez‐Puebla Ramon A.15ORCID

Affiliation:

1. Department of Physical and Inorganic Chemistry Universitat Rovira i Virgili Tarragona 43007 Spain

2. CINBIO Universidade de Vigo Vigo 36310 Spain

3. Institute of Fundamental and Frontier Sciences University of Electronic Science and Technology of China Chengdu 610054 China

4. Department of Physics and Astronomy Ohio University Athens OH 45701 USA

5. ICREA—Institució Catalana de Recerca i Estudis Avançats Barcelona 08010 Spain

Abstract

AbstractPlasmonic metal–organic frameworks (plasmonic‐MOFs) ingeniously meld the homogeneous and vast porosity of MOFs with the distinctive plasmonic characteristics of metallic nanoparticles (NPs), creating a powerful synergy. This innovative combination is leveraged for enhanced plasmon‐induced hot‐electron photocatalysis, particularly within polystyrene beads adorned with silver nanoparticles (AgNPs) and encapsulated by zeolitic imidazolate framework‐8 (ZIF‐8). The strategic incorporation of AgNPs into this composite material generates hot carriers, significantly enhancing the catalytic performance of ZIF‐8. This approach not only exemplifies the potential for advanced photocatalytic processes of MOFs, but also paves the way for groundbreaking applications in environmental remediation and sustainable chemistry.

Funder

Agència de Gestió d'Ajuts Universitaris i de Recerca

Xunta de Galicia

Agencia Estatal de Investigación

Publisher

Wiley

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