Affiliation:
1. School of Chemistry and Chemical Engineering Nanjing University of Science and Technology Nanjing 210094 P. R. China
2. School of Chemistry and Chemical Engineering Yangzhou University Yangzhou 225009 P. R. China
3. Eco‐Materials and Renewable Energy Research Center (ERERC) School of Physics Nanjing University Nanjing 210093 P. R. China
4. School of Science and Engineering The Chinese University of Hong Kong Shenzhen 518172 P. R. China
5. School of Chemical and Environmental Engnieering Anhui Polytechnic University Wuhu 241002 P. R. China
Abstract
AbstractThe establishment of green and environmental friendly sunlight‐driven organic reactions has received increasing attention since the 21st century. By virtue of their functional designability, micromesoporous structure, and thermal/chemical stability, porous organic polymers (POPs) have exhibited enormous promise in photocatalytic organic reactions as ideal potential alternatives to conventional small molecule and inorganic semiconductor catalysts. In particular, amorphous POPs are simplified in terms of preparation conditions and process flow. Herein, various amorphous POP materials based on polymers of intrinsic microporosity, hypercrosslinked polymers, conjugated microporous polymers, and porous aromatic frameworks are reviewed, while typical synthetic strategies are briefly introduced. It also highlights an overview of the research progress in photocatalytic oxidation, coupling, reduction, cycloaddition, and polymerization reactions at home and abroad in recent years. Finally, the challenges and prospects for future research on amorphous POPs are presented.
Funder
National Natural Science Foundation of China
Natural Science Foundation of Jiangsu Province
Fundamental Research Funds for the Central Universities
Subject
Electrochemistry,Condensed Matter Physics,Biomaterials,Electronic, Optical and Magnetic Materials