Grayscale to Multicolor Laser Writing Inside a Label‐Free Metal‐Organic Frameworks

Abstract

AbstractDirect laser writing (DLW), being a universal tool for fast creating colorless/color images on different substrates, still suffers from simultaneous writing grayscale and color images inside the transparent media. Here, it is discovered that a unique set of porosity, coordination bonding between organic and inorganic building blocks, and the lack of inversion symmetry of the label‐free metal‐organic frameworks (MOFs), on the one hand, provides the possibility of laser writing the grayscale images through the amorphization/carbonization. On the other hand, the reduction of the laser writing power leads to controllable creation of color images via defect formation with sub‐diffraction resolution inside the MOF crystals. The latter is due to the processes of self‐absorption of generated optical harmonics by nonlinear MOFs within the visible spectral range. As a result, simultaneous grayscale and multicolor writing of QR codes and images are demonstrated with up to 400 nm resolution inside optically transparent MOF crystals, thereby discovering a new family of functional materials for DLW.