Affiliation:
1. Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials (Ministry of Education) Shandong University Jinan 250061 China
2. School of Materials Science and Engineering Nankai University Tianjin 300350 China
3. Institute of Advanced Electrical Materials Qingdao University of Science & Technology Qingdao 266042 China
4. College of Ocean Science and Engineering Shanghai Maritime University Shanghai 201306 China
Abstract
Recently, metamaterials with fascinating dielectric behavior have drawn much attention for their potential applications. Herein, percolating graphene/poly(vinylidene fluoride) (GR/PVDF) composites consisting of GR sheets homogeneously dispersed in PVDF matrix are fabricated via hot‐pressing method in 20 Hz–1 MHz frequency regions, of which simultaneously realizing negative permittivity with low percolation threshold. It is demonstrated that the negative permittivity of GR/PVDF composites is resulted from the low‐frequency plasma oscillation of free electrons, and a universal regulatory mechanism of the Drude model is analyzed. At the same time, rapid formative 3D GR conductive networks contributed to the low percolation threshold (7.78 wt%) of composites. Moreover, it is shown that electrical percolation occurs in samples as GR content exceeds percolation threshold, indicating a typical metal‐like behavior. In addition, the reactance is discussed according to the equivalent circuit analysis. This work constructed the metacomposites with low filler content, which is a benefit for practical applications in electromagnetic devices.
Funder
National Natural Science Foundation of China
Subject
Condensed Matter Physics,General Materials Science
Cited by
1 articles.
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