Affiliation:
1. College of Chemistry and Chemical Engineering Southwest Petroleum University Chengdu P. R. China
2. Sichuan Guangya Polymer Chemical Co., Ltd Chengdu P. R. China
Abstract
AbstractIn this investigation, a new micro‐crosslinked anionic polymer resistant to elevated temperature and high salinity, PKDASN, was synthesized using 3‐chloropropyltriethoxysilane (KMB703), N, N‐Dimethylacrylamide (DMAM), 2‐acrylamido‐2‐methylpropanesulfonic acid (AMPS), N‐vinyl caprolactam (NVCL), and sodium (4‐vinyl phenyl)methanesulfonate (SVM) employing free radical polymerization in a water‐based solution. The structure of PKDASN was analyzed using Fourier‐transform infrared spectroscopy, nuclear magnetic resonance spectroscopy, and X‐ray photoelectron spectroscopy, while its microstructure was analyzed using scanning electron microscopy. Thermogravimetric analysis showed that the pyrolysis temperature of PKDASN was above 294°C. Adding KMB703 enables the polymer to form a dense and stable spatial network. This intensified polymer network could interact with bentonite via intermolecular force and Coulomb force and form a dual grid structure, which presents impressive stability and control of filtration in saltwater. This is mainly achieved through creating a “silane coupling layer” on the particle surface by KMB703, which facilitates the crosslinking and aggregation of the polymer, thereby reinforcing the polymer's framework. This implies that under high‐temperature conditions of 230°C, 3 wt% PKDASN can improve the filtration effectiveness of drilling fluids and exhibit resistance to 15 wt% NaCl contamination. American Petroleum Institute filtration(FLAPI) and High temperature and high pressure filtration(FLHTHP) values were 4.6 and 23.0 mL, respectively. Therefore, this investigation provides a novel approach to utilizing the designated silane agent for the advancement of filtration loss additives in drilling fluids resistant to elevated temperature and high salinity.