Photoredox‐Catalyzed Deconstructive Thiolation and Selenylation of Pro‐Aromatic Carbocycles-Reference-Cited by-同舟云学术

Photoredox‐Catalyzed Deconstructive Thiolation and Selenylation of Pro‐Aromatic Carbocycles

Published:2025-04-28 Issue:11 Volume:17 Page:
ISSN:1867-3880
Container-title:ChemCatChem
language:en
Short-container-title:ChemCatChem

Author:

Yang Wen‐Peng¹,Li Jia‐Yi¹,Liu Hong‐Fei¹,Miao Hong‐Jie¹,Duan Xin‐Hua¹²^ORCID,Guo Li‐Na¹

Affiliation:

1. Department of Chemistry School of Chemistry Xi'an Key Laboratory of Sustainable Energy Material Chemistry and Engineering Research Center of Energy Storage Materials and Devices Ministry of Education Xi'an Jiaotong University Xi'an 710049 China

2. State Key Laboratory of Applied Organic Chemistry Lanzhou University Lanzhou 730000 China

Abstract

AbstractPhotoredox‐catalyzed aromatization‐driven deconstructive thiolation and selenylation of spiro‐dihydroquinazolinones are presented. This method, which involves C─C bond cleavage and C─S or Se bond formation, provides a facile approach to synthesizing remote and site‐specific thiolated and selenated quinazolin‐4(3H)‐ones with good yields and functional group compatibility. A probable radical pathway is proposed for this transformation.

Funder

National Natural Science Foundation of China

Publisher

Wiley

Link

https://chemistry-europe.onlinelibrary.wiley.com/doi/pdf/10.1002/cctc.202500104

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