Recent Progress in the Selective Hydrodeoxygenation of 5‐Hydroxymethylfurfural to 2,5‐Dimethylfuran With Metal‐Containing Catalysts

Author:

Gautam Rahul1,Li Hu2,Saravanamurugan Shunmugavel1ORCID

Affiliation:

1. Laboratory of Bioproduct Chemistry Center of Innovative and Applied Bioprocessing Sector-81 (Knowledge City) 140306 Mohali Punjab India

2. State Key Laboratory of Green Pesticide Key Laboratory of Green Pesticide and Agricultural Bioengineering Ministry of Education State-Local Joint Laboratory for Comprehensive Utilization of Biomass Center for R&D of Fine Chemicals Guizhou University 550025 Guiyang Guizhou China

Abstract

AbstractLiquid fuel, such as 2,5‐dimethylfuran (DMF), from biomass, is an efficient, potential alternative to fossil‐based fuels due to its exceptional properties, including lower volatility, a remarkable octane number, heightened energy density, and immiscibility with water. DMF can be the starting substrate for producing bio‐based p‐xylene through the Diels‐Alder reaction with ethylene to produce biobased polyethylene terephthalate (PET). This review, thus, discusses the catalytic role of various precious and non‐precious metals on different supports, such as carbon, metal‐oxide, zeolite, and hydrotalcite, for the production of DMF via catalytic hydrodeoxygenation (HDO) of 5‐hydroxymethylfurfural (HMF) based on the previously reported literature. Various characteristic properties of the employed catalytic materials, such as particle size, metal‐support and substrate interaction, surface area, porosity, and acidic and basic sites, are delineated, playing a crucial role in the HDO of HMF to DMF. The influence of various reaction parameters, such as hydrogen atmosphere, solvents‐ including hydrogen donor solvents‐ and temperature are also discussed.

Publisher

Wiley

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