Affiliation:
1. Okinawa Institute of Science and Technology Graduate University Onna-son, Kunigami-gun 904-0495 Okinawa Japan
2. Arbuzov Institute of Organic and Physical Chemistry FRC Kazan Scientific Center Russian Academy of Sciences Kazan 420088 Russian Federation
Abstract
AbstractWe describe versatile and practical light‐promoted C−N and C−O cross‐coupling reactions catalyzed by NiII complexes supported by 2,7‐dimethyl‐1,8‐naphthyridine ligand. Using the same Ni catalyst and visible light irradiation, both C−O and C−N coupling reactivity was observed without additional photocatalysts. These results demonstrate that Ni naphthyridine complexes represent a versatile catalytic motif for photoredox nickel catalysis alternative to commonly used bipyridines or multidentate ligands.
Funder
Okinawa Institute of Science and Technology Graduate University
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Catalysis