Affiliation:
1. College of Chemistry and Materials Engineering Wenzhou University Wenzhou 325035 P. R. China
Abstract
AbstractA transition‐metal‐free method is disclosed for the construction of selenylated spirocyclohexadienones via cascade cyclization/dearomatization reaction of aryl phenol‐tethered alkynes with diselenides. The high efficiency of this protocol was demonstrated by room temperature, simple reaction conditions, and the ability to enable a gram‐scale synthesis. The experiment results implied that the dearomatization process proceeded in a radical way.
Funder
National Natural Science Foundation of China
Natural Science Foundation of Zhejiang Province
Subject
Organic Chemistry,Physical and Theoretical Chemistry