Hybrid Nanoarchitectronics of Tantalum Oxide‐Coated Gold Nanoparticles as Localized Surface Plasmon Resonance‐Based Sensors for Volatile Organic Compounds Detection

Author:

Changpradub Kiratikarn1ORCID,Threrujirapapong Thotsaphon1,Lertvanithphol Tossaporn2,Amarit Ratthasart2,Wongpanya Kruawan2,Tantiwanichapan Khwanchai2,Wutikhun Tuksadon3,Klamchuen Annop3,Nakajima Hideki4,Horprathum Mati2ORCID

Affiliation:

1. Department of Materials and Production Technology Engineering KMUTNB Bangkok 10800 Thailand

2. Opto‐Electrochemical Sensing Research Team National Electronics and Computer Technology Center Klong Luang Pathum Thani 12120 Thailand

3. Nanocharacterization Research Team National Nanotechnology Center Klong Luang Pathum Thani 12120 Thailand

4. Synchrotron Light Research Institute Maung Nakhon Ratchasima 30000 Thailand

Abstract

Herein, a localized surface plasmon resonance‐based sensor for volatile organic compounds (VOCs) detection is developed. The sensors are fabricated as a hybrid nanostructure of gold nanoparticles coated with a tantalum oxide (TaO) thin film on a glass slide substrate through magnetron sputtering and thermal solid‐state dewetting techniques. The thickness of the TaO film varies between 10 and 70 nm. The optical properties of samples are characterized by UV‐Vis‐NIR spectrophotometry, while their morphologies are confirmed via transmission electron microscopy. The results show the shift of the minimum optical transmittance related to the TaO thickness. Electrical field simulations are performed to predict the sensitivity of the prepared samples for VOCs detection. In addition, the sensors are tested with different VOCs, including formaldehyde, isopropanol, acetone, and methanol, which show good potential for practical applications.

Publisher

Wiley

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