Topological Metal MoP Nanowire for Interconnect

Author:

Han Hyeuk Jin123,Kumar Sushant4,Jin Gangtae12ORCID,Ji Xiaoyang5,Hart James L.126,Hynek David J.12,Sam Quynh P.6,Hasse Vicky7,Felser Claudia7,Cahill David G.5,Sundararaman Ravishankar4,Cha Judy J.126ORCID

Affiliation:

1. Department of Mechanical Engineering and Materials Science Yale University New Haven CT 06511 USA

2. Energy Sciences Institute Yale West Campus West Haven CT 06516 USA

3. Department of Environment and Energy Engineering Sungshin Women's University Seoul 01133 South Korea

4. Department of Materials Science and Engineering Rensselaer Polytechnic Institute Troy NY 12180 USA

5. Department of Materials Science and Engineering University of Illinois Urbana‐Champaign Urbana IL 61801 USA

6. Department of Materials Science and Engineering Cornell University Ithaca NY 14853 USA

7. Max Planck Institute for Chemical Physics of Solids 01187 Dresden Germany

Abstract

AbstractThe increasing resistance of copper (Cu) interconnects for decreasing dimensions is a major challenge in continued downscaling of integrated circuits beyond the 7 nm technology node as it leads to unacceptable signal delays and power consumption in computing. The resistivity of Cu increases due to electron scattering at surfaces and grain boundaries at the nanoscale. Topological semimetals, owing to their topologically protected surface states and suppressed electron backscattering, are promising candidates to potentially replace current Cu interconnects. Here, we report the unprecedented resistivity scaling of topological metal molybdenum phosphide (MoP) nanowires, and it is shown that the resistivity values are superior to those of nanoscale Cu interconnects <500 nm2 cross‐section areas. The cohesive energy of MoP suggests better stability against electromigration, enabling a barrier‐free design . MoP nanowires are more resistant to surface oxidation than the 20 nm thick Cu. The thermal conductivity of MoP is comparable to those of Ru and Co. Most importantly, it is demonstrated that the dimensional scaling of MoP, in terms of line resistance versus total cross‐sectional area, is competitive to those of effective Cu with barrier/liner and barrier‐less Ru, suggesting MoP is an attractive alternative for the scaling challenge of Cu interconnects.

Funder

Semiconductor Research Corporation

Publisher

Wiley

Subject

Mechanical Engineering,Mechanics of Materials,General Materials Science

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