A one‐pot, stereoselective synthesis of 2‐ethoxycarbonyl‐substituted 1,3‐dienes and 1,3‐enynes by hydrostannylation–Stille tandem reaction of tributyltin hydride with alkynyl esters and alkenyl or alkynyl halides-Reference-Cited by-同舟云学术

A one‐pot, stereoselective synthesis of 2‐ethoxycarbonyl‐substituted 1,3‐dienes and 1,3‐enynes by hydrostannylation–Stille tandem reaction of tributyltin hydride with alkynyl esters and alkenyl or alkynyl halides

Published:2009-05-13 Issue:6 Volume:23 Page:229-234
ISSN:0268-2605
Container-title:Applied Organometallic Chemistry
language:en
Short-container-title:Applied Organom Chemis

Author:

Cai Mingzhong,Fang Xiaoniu,Dai Ruchun,Zha Lingfang

Abstract

Abstract2‐Ethoxycarbonyl‐substituted 1,3‐dienes and 1,3‐enynes can be stereoselectively synthesized in one pot under mild conditions, in good yields, by the palladium‐catalyzed hydrostannylation of alkynyl esters, followed by Stille coupling with alkenyl or alkynyl halides, respectively. Copyright © 2009 John Wiley & Sons, Ltd.

Publisher

Wiley

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/aoc.1502

Reference69 articles.

1. A facile and highly stereoselective synthesis of (2E)-, (2E,4E)-unsaturated amides and related natural products

2. Highly Stereoselective Synthesis of (1E)‐2‐Methyl‐1,3‐dienes by Palladium‐Catalyzed trans‐Selective Cross‐Coupling of 1,1‐Dibromo‐1‐alkenes with Alkenylzinc Reagents

3. The Wittig reaction: comments on the mechanism and application as a tool in the synthesis of conjugated dienes

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