Affiliation:
1. Max-Planck-Institut für Kohlenforschung Kaiser-Wilhelm-Platz 1 45470 Mülheim an der Ruhr Germany
2. University of Manchester Oxford Road M13 9PL Manchester UK
Abstract
AbstractIn this article we report that a cationic version of Akiba's BiIII complex catalyzes the reduction of amides to amines using silane as hydride donor. The catalytic system features low catalyst loadings and mild conditions, en route to secondary and tertiary aryl‐ and alkylamines. The system tolerates functional groups such as alkene, ester, nitrile, furan and thiophene. Kinetic studies on the reaction mechanism result in the identification of a reaction network with an important product inhibition that is in agreement with the experimental reaction profiles.
Funder
Natural Sciences and Engineering Research Council of Canada
HORIZON EUROPE European Research Council
Verband der Chemischen Industrie
Max-Planck-Gesellschaft
Subject
General Chemistry,Catalysis
Cited by
2 articles.
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