Metal‐Mediated Synthesis of a Mixed Arduengo‐Fischer Carbodicarbene Ligand-Reference-Cited by-同舟云学术

Metal‐Mediated Synthesis of a Mixed Arduengo‐Fischer Carbodicarbene Ligand

Published:2024-07-19 Issue:35 Volume:63 Page:
ISSN:1433-7851
Container-title:Angewandte Chemie International Edition
language:en
Short-container-title:Angew Chem Int Ed

Author:

Kooij Bastiaan¹^ORCID,Chen Damien W.¹,Fadaei‐Tirani Farzaneh¹,Severin Kay¹^ORCID

Affiliation:

1. Institut des Sciences et Ingénierie Chimiques Ecole Polytechnique Fédérale de Lausanne (EPFL) 1015 Lausanne Switzerland

Abstract

AbstractCarbodicarbenes are strong C‐donor ligands, which have found numerous applications in organometallic and main group element chemistry. Herein, we report a structurally distinct carbodicarbene ligand, which is formed by dinitrogenative coupling of a Fischer carbene complex with an N‐heterocyclic diazoolefin. The resulting carbonyl complex serves as a stable source for the mixed Arduengo‐Fischer carbodicarbene ligand. Facile ligand transfer reactions were demonstrated to occur with gold(I), copper(I), palladium(II), and rhodium(I) complexes.

Funder

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

Publisher

Wiley

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.202407945

Reference85 articles.

1. C(NHC)2: Divalent Carbon(0) Compounds with N-Heterocyclic Carbene Ligands-Theoretical Evidence for a Class of Molecules with Promising Chemical Properties

2. Synthesis of an Extremely Bent Acyclic Allene (A “Carbodicarbene”): A Strong Donor Ligand

3. Coordination Chemistry of Ene-1,1-diamines and a Prototype “Carbodicarbene”

4. An alternative way of describing the electronic situation in carbodicarbenes is by treating the carbene flanking groups as ligands with dative bonds towards the central carbon atom:

5. Carbones and Carbon Atom as Ligands in Transition Metal Complexes

Cited by 2 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Cycloadditions of Diazoalkenes with P₄ and tBuCP: Access to Diazaphospholes;Angewandte Chemie International Edition;2024-08-20

2. Nitrous oxide as diazo transfer reagent;Chemical Science;2024