Some hydrogen abstraction reactions of the trichloromethyl radical-Reference-Cited by-同舟云学术

Some hydrogen abstraction reactions of the trichloromethyl radical

Published:1971-05 Issue:3 Volume:3 Page:283-289
ISSN:0538-8066
Container-title:International Journal of Chemical Kinetics
language:en
Short-container-title:Int J of Chemical Kinetics

Author:

Wampler Fred B.,Kuntz Robert R.

Abstract

AbstractThe gas phase photolysis of CCl4 in the presence of several alkanes has been used to obtain Arrhenius parameters for the abstraction of hydrogen atoms by the CCl3 radical:

magnified image

The following log k4 values were obtained:

RH log k4 c‐C5H10,

n‐C6H14

2,3‐Dimethylbutane

c‐C7H14

Methylcyclohexane

c‐C8H16

The results are compared to those for CH3 and CF3 radicals.

Publisher

Wiley

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/kin.550030308

Reference11 articles.

1. Free radical substitution in aliphatic compounds. Part 11—Reaction of trichloromethyl radicals with n-butane

2. Free Radical Substitution in Aliphatic Compounds. Part IV. The Reaction of Trichloromethyl Radicals with Propane, n‐Butane and Iso‐Butane

3. M. L.WhiteandR. R.Kuntz Int. J. Chem. Kinet. 00 000 (0000).

4. J.JarvieandR.Kuntz private communication.

5. The Photolysis of Carbon Tetrachloride in the Presence of Ethane and Ethylene

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