High Performance Piezoelectric Nanogenerators Based on Polyvinylidene Fluoride‐Graphene Nanoribbon Composite Thin Films

Abstract

AbstractIn this study, a highly efficient, sensitive, and lightweight piezoelectric nanogenerator (PENG) is developed using graphene nanoribbons (GNRs) incorporated into the polyvinylidene fluoride (PVDF) matrix. Unzipping multi‐walled carbon nanotubes is an effective and scalable strategy for synthesizing graphene nanoribbons. The synthesized GNRs are employed to prepare nanometer‐scale piezoelectric polymer composite films showing higher piezoelectric performance than neat PVDF. The impact of GNR concentration in the PVDF matrix on the electroactive phase content and piezoelectric properties of the composites is systematically investigated. X‐ray diffraction (XRD) and Fourier‐transformed infrared spectroscopy (FT‐IR) analysis demonstrate an increase in the electroactive β and γ phases of PVDF by incorporating GNRs in the composites. With the optimized concentration of GNRs (1 wt%), the fabricated piezoelectric device can generate open‐circuit voltage and an output power density of 26 V and 16.52 µWcm2, respectively. It is also found that the PVDF‐GNR 1 nanogenerator can be used to generate electrical power by converting mechanical energy from different human activities such as wrist bending, palm tapping, and toe tapping. The findings indicate that (PVDF‐GNR 1) PENG can be applied in self‐powered portable and wearable electronic devices.