Improving the Thermal Aging Resistance of γ‐Vulcanized Polybutadiene Rubber (BR)/Nature Rubber (NR) Blends with Sulfur Added

Abstract

In this paper, sulfur was added into polybutadiene rubber/nature rubber (BR/NR) blends for improving the resistance of thermal aging. BR/NR blends with sulfur were vulcanized by 60Co γ radiation with different irradiation doses. Afterwards, the specimens underwent thermal aging by using air oven, the non‐aged specimens without such process. It was found that the crosslink degree of BR/NR blends increased with the increase in the irradiation dose, according to the results of gel and molecular weight between crosslinks (Mc). Furthermore, the crosslink degree of BR/NR blends increased after thermal aging. This made the mechanical properties and initial degradation temperature (IDT) of aged BR/NR blends improve. Sulfur could improve thermal resistance of γ‐irradiated BR/NR blends. Finally, the possible mechanism of improved crosslink degree in aged BR/NR blends was illuminated in the paper.