Engineering of Multidimensional Core-Shell Perovskite Precursors to Obtain Superior Luminescence and Incorporating in Luminescent Solar Concentrators

Abstract

The luminescence feature of perovskite NPs with high PLQY directs them to lighting and display applications. 2D ${\left(\text{A}\right)}_2\text{M}{\text{A}}_{n-1}\text{P}{\text{b}}_n\text{B}{\text{r}}_{3n+1}$ ($n=1-6$) perovskites with A as octylammonium and benzylammonium cations are synthesized by the LARP method, in which the highest PL emission is attained to the $n=6$ sample with benzylamine cation. XRD results reveal the appearance of diffraction peaks related to 3D perovskites with increasing $n$ value. Mixing 3D perovskites with 2D ones leads to the formation of core-shell $\text{MAPbB}{\text{r}}_3-{\left(\text{A}\right)}_2\text{M}{\text{A}}_{n-1}\text{P}{\text{b}}_n\text{B}{\text{r}}_{3n+1}$ ($n=1-6$) nanostructures, confirmed by TEM images and optical properties. Incorporation of Zn to core-shell perovskites improves the PL intensity and induces higher crystallinity. A blue shift in absorption and emission spectra of Zn-doped perovskites is observed. The highest PLQY (94%) is attributed to the Zn-doped core-shell perovskite with $n=6$ among the all-synthesized samples. Luminescent solar concentrators with thicknesses of 2 mm and 5 mm are fabricated with benzylamine-based perovskites, because of their greater PLQY versus octylamine-based perovskites. The performance of LSC devices is boosted for the LSC with 5 mm thickness. The relative PCE obtained for the core-shell perovskite-based LSC with thickness of 5 mm reaches to almost 60%.