Supported Ionic Liquids and their Applications in Organic Transformations

Author:

Singh Pradeep Pratap1ORCID,Ambika 2ORCID

Affiliation:

1. Department of Chemistry, Swami Shraddhanand College, University of Delhi, Delhi, India

2. Department of Chemistry, Hansraj College, University of Delhi, Delhi, India

Abstract

Abstract: Ionic liquids are one of the greener solvents which have emerged as a replacement for toxic and harmful volatile organic solvents. In the past decade, the concept of supported ionic liquids (SILs) has attracted the attention of the scientific community due to their unique chemical and phys-ical properties. SILs can be synthesized by coating a thin layer of IL film onto/into the surface of solid support. They can be classified as supported IL phase catalyst, solid catalyst with IL and sup-ported IL catalysis. SILs demonstrated the combined properties of both heterogeneous and homoge-neous catalysts. These ILs offer several advantages such as enhanced stability, reusability, recovera-bility, easy product isolation, absence of IL leaching, as compared to conventional solvents. In this review, various aspects of SILs, classification, method of preparation and their applications in var-ious organic transformations such as cross-coupling reactions, oxidation, reduction, synthesis of dif-ferent heterocyclic compounds, biocatalytic reactions etc., have been discussed.

Publisher

Bentham Science Publishers Ltd.

Subject

Organic Chemistry,Biochemistry

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