Water-Zeolite Interfaces for Controlling Reaction Routes in Fischer- Tropsch Synthesis of Alternative Fuels

Author:

Mordkovich Vladimir Z.1ORCID,Sineva Lilia V.1

Affiliation:

1. Technological Institute for Superhard and Novel Carbon Materials, Troitsk, Moscow, Russian Federation

Abstract

Background: The Fischer-Tropsch Synthesis (FTS) remains an important process for motor fuel production from CO and H2. The composition of the FTS products (hydrocarbon mixtures) depends on the properties of a catalyst and on the process conditions. Summary: The introduction of zeolites into catalytic systems can alter the molecular weight distribution paving the way to tailor-made fuels, as was revealed by recent research results produced in the laboratories worldwide. The AlO4 and SiO4 tetrahedrons, which constitute the zeolites, are able to transfer electrons and ions in a way, which makes water-zeolite interfaces capable of initiating active carbonium ions. It was shown in a number of works that the water-zeolite interface plays a key role in diverting the FTS from the classical route. Conclusion: This review gives a critical analysis of literature data on the role of water-zeolite interfaces on FTS cobalt catalysts and on the interactions of hydrophobic and hydrophilic zeolites with water.

Funder

Ministry of Science and Higher Education of the Russian Federation

Publisher

Bentham Science Publishers Ltd.

Subject

General Medicine

Reference151 articles.

1. Catalysis in the Refining of Fischer-Tropsch Syncrude. de Klerk, A., Furimsky, E. Ed. RSC Publishing Cambridge, 2010. Van Steen, E., Claeys, M. Fischer-Tropsch Catalysts for the Biomass‐to‐Liquid (BTL). Process Chem Eng Technol 2008,31,655-667

2. Lapidus A.L.; Krylova A.Yu.; Mikhailova Ya.V.; Sineva L.V.; Erofeev A.B.; Effect of the nature of the support of a cobalt catalyst on the synthesis of hydrocarbons from CO, H2, and C2H4

3. Rossetti I.; Gambaro C.; Calemma V.; Hydrocracking of long chain linear paraffins. Chem. Eng. J., 2009, 154, 295-315. Gamba, S., Pellegrini, L.A., Calemma, V., Gambaro, C. Liquid fuels from Fischer-Tropsch wax hydrocracking: Isomer distribution. Catal. Today, 2016, 156, 58-67. Jiang, J., Yang, C., Lu, Z., Ding, J., Lia, T., Lu, Y., Cao, F. Characterization and application of a Pt/ZSM-5/SSMF catalyst for hydrocracking of paraffin wax. Catal. Commun., 2015, 60, 1-6. Calemma, V., Gambaro, C., Parker Jr., W.O., Carbone, R., Giardino R., Scorletti, P. Middle distillates from hydrocracking of FT waxes: Composition, characteristics and emission properties. Catal Today 2010,149,40-49

4. Hodala J.A.; Jung J-S.; Yang E-H.; Hong G.H.; Noh Y.S.; Moon D.J.; Hydrocracking of FT-wax to fuels over non-noble metal catalysts. Fuel 2016,185,339-347

5. Weitkamp J.; Ernst S.; Factors Influencing the Selectivity of Hydrocracking in Zeolites. Guidelines for Mastering the Properties of Molecular Sieves Plenum Press: New York 1990, 4, pp. 343- 354 Weitkamp, J. Catalytic Hydrocracking Mechanisms and Versatility of the Process. ChemCatChem; Plenum Press: New York, 2012, 4, pp. 292-,Kinger, G.; Vinek, H. N-nonane hydroconversion on Ni and Pt containing HMFI, HMOR and HBEA. Appl. Catal; Plenum Press: New York, 2001, 4, pp. 139-

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