Author:
Saraswathi Mandapati,Miller Jack M.,Jones Tim R.B.
Abstract
The mass spectra of tris(perfluorophenyl)phosphine obtained under negative ion Fast Atom Bombardment conditions showed formation of an unusual ion at m/z 397 attributed to ((C6F5)2PO2)−. The matrix effects involved in this reaction are discussed. Negative ion FAB spectra of tris(perfluorophenyl)arsine and tris(perfluorophenyl)stibine are also reported. Keywords: pentafluorophenylphosphine, -arsine, -stibine; negative ion FABMS; matrix effects.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis