Abstract
Irradiation of ethyl-1-C14 iodide gave ethyl-2-C14 iodide with Gr of 0.27–0.28 for samples that were either deaerated or not deaerated. Addition of 1% by weight of iodine before irradiation decreased the extent of rearrangement to nearly zero. The occurrence of 1,2-hydrogen shifts in ethyl radicals outside of the spurs, which may be susceptible to scavenger action, is suggested as a possible path which would lead to the ethyl-2-C14 iodide.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
4 articles.
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