Author:
Armstrong Rosemary J.,Weiler Larry
Abstract
The epoxy allysilanes 7 and 16 were synthesized by stereoselective routes from β-keto esters and cyclized with Lewis acids in good yield. The monocyclic product from 7 was converted into (±)-karahana ether (10), and the bicyclic product from 20 was used in a synthesis of the 3-hydroxylabdadienoic acid 24b.[Formula: see text]
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
63 articles.
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